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Droplets don’t have to be round – here’s one squished into a square

Drops of liquid are usually round, but now we’ve found out how to make square droplets by squashing liquid between two elastic films stretched in different directions
Don't be a square
Don’t be a square – or do
R. Schulman/McMaster University

DROPS of liquid are usually round, but they don’t have to be. Researchers sandwiched drops of glycerol between stretched elastic films to see what shapes they could make – and were surprised to produce a square.

Rafael Schulman and Kari Dalnoki-Veress at McMaster University in Canada started with a thin film lying flat on a silicon surface, and deposited a droplet around 100 nanometres in diameter on top. Then they placed a second film over the droplet. When the tension in the top film was equal in all directions, the droplet’s outline was circular, viewed from above. From the side, the droplet looked like a tiny dome sitting on a flat surface.

When they stretched the top film in one direction before placing it on the droplet, the liquid took on an oval shape, elongating in the same direction as the film.

Finally, they stretched the bottom film in one direction and the top film in another, at 90 degrees to the first. Now the trapped droplet took on a square shape with slightly rounded corners.

“We were surprised to see this,” says Dalnoki-Veress. “The lowest energy state for a liquid droplet is a round spherical cap, typically. That’s why a droplet on a spider web is round, that’s why a droplet on a leaf is a little spherical cap. But here you have an example of nature creating a structure which is completely counter-intuitive.”

Now that we understand how to manipulate liquids into shapes between soft films, we can make nearly any shape, symmetrical or not, by playing with the tension of the films, says Dalnoki-Veress.

This method could be used to make arrays of small lenses that focus light in unusual ways. When the researchers shone a laser through the square droplet, for example, they found that it made a cross-shaped pattern.

Physical Review Letters

Topics: Materials